CLIMATE HISTORY AND GEOLOGY


5.  GLOBAL WARMING
AND GREENHOUSE GASES




The heat balance of the Earth is a delicate thing, and we must take whatever actions are possible to ensure that we don't upset that balance.  The natural balance, which takes radiative heat from the Sun, redistributes it, and re-emits part of the heat back into space, is what makes life possible on Earth.  The heat balance of the planets Venus and Mars became disrupted early in their history; so the surface of Venus is like a very hot oven, and Mars is too cold to sustain any complex life as we know it. 

The development of complex life on Earth is a direct consequence of the relatively stable heat balance, and the retention of an atmosphere and oceans.  That balance is largely due to greenhouse gases in the atmosphere.  Those greenhouse gases are a blessing; but too much can cause unwanted warming.  It has been well documented that the Earth has recently entered a period of gradual Global Warming.  This promises to be the greatest scientific, engineering, poltical, social, and economic challenge of the twenty-first century.




CHANGES IN THE CONCENTRATION OF
GREENHOUSE GASES


The onset of global warming has called attention to the importance of "greenhouse gases", particularly carbon dioxide (CO2), methane (CH4), and water vapor (H2O).  The first two are byproducts of man's activities; and have been continuously increasing since they were first measured.  Research workers have attacked the problem using geochemical models and various kinds of paleoclimatic data, particularly from ice cores in Greenland and Antarctica.  The results are highly dependent on the other data that went into the geochemical models, such as temperatures, amount of ice locked in glaciers, etc., but they do indicate some interesting trends.

There are two major research problems associated assessing the effects of greenhouse gases:

  1. Accounting for the role of greenhouse gases in the climates of geological times, and
  2. Predicting the warming to be expected in the future.

One of the great problems with the Milankovitch theory of glacial cycles is its inability to account for the long ice-free periods, which may have lasted as long as 40 million or more years.  Calculations for the past 100 million years indicate that the CO2 concentration during the time of the dinosaurs may have been as great as 90 times the values at the beginning of the 20th century.  The concentrations dropped continuously though the Cretaceous period, to a value comparable with present values at the time of the dinosaurs' extinction, about 65 million years ago.  The concentration rose again during the early Cenozoic era to several times present values, but fell dramatically at the beginning of the ice ages.  After the early Cenozoic, beginning about 50 million years ago, the climate began to gradually cool—a trend that continued until the present time.

Research workers have been impressed with the instability of the Earth's climate, and the complexity of the interrelationships between the various components.  During times when the Earth was quite warm, the amount of water in glaciers and ice caps has been almost negligible.  At the same time the amount of water vapor in the atmosphere had increased.  Water can act as a greenhouse gas in its vapor state, thus contributing to the warming, or it can cause cooling if dense clouds form.

Changes in gases, heatingThe "other" greenhouse gas, water vapor, could have been a major factor in maintaining the high temperatures of periods in the distant past, such as the period from the Jurassic through the early Cenozoic.  The relative amounts of atmospheric water in clouds and in the vapor phase depends strongly on the atmospheric circulation.  In times when there was a reduced difference between the equator and the poles, there might have been more water vapor in the atmosphere, leading to a positive feedback which raised the temperatures even more.

After the continental glaciers began to melt, in response to increased solar heating, the warming process was accelerated by increases in the amount of water vapor and CO2 in the air.  The warming was also accelerated as more land was exposed to absorb solar energy.  The figure schematically shows the progress of those effects along with the increase in solar radiation during the summer.




RADIATION BALANCE
OF THE EARTH


The greenhouse effect is easily explained, though most textbooks on weather and climate do not present the whole story.  The temperature of the Sun's radiating surface is about 6000 Kelvin (a Kelvin degree is the same as a Celsius, or Centigrade degree, or 9/5 times a Fahrenheit degree, the Kelvin scale begins at absolute zero = -273 C = -459 F).  The peak radiation is at a wavelength of about 5.5 micron, which corresponds to yellow-green light in the middle of the visible spectrum.  The total radiant energy emitted by a hot body like the Sun is proportional to the 4th power of the temperature.  A tiny change in the temperature would result therefore in a large increase in the total radiated energy.  Fortunately the Sun's output is quite constant; though a tiny change in the average temperature might have caused the Little Ice Age.

If the Earth were completely surrounded by a radiating body at a temperature of 6000 K it would attain a radiative equilibrium temperature of 6000 K.  This is equivalent to being in the center of an intensely hot oven.  Of course the Earth is not fully surrounded by the Sun; in fact the Sun fills only 4.76 millionths of the entire sky (including both the night and day hemispheres).  The radiant energy received at the Earth's surface is therefore "diluted" by the same proportion. 

In radiative equilibrium the Earth must radiate back into space the same amount of energy it absorbs from the Sun.  The laws of radiant energy balance tell us that the average radiant energy emitted by the Earth is proportional to the Earth's effective temperature to the 4th power.  Thus the emission temperature of the Earth must be Te = (Tsun times (0.00000476)) to the 1/4 power.  If there were no atmosphere, and the Earth radiated energy like a theoretical black body, the average temperature of the Earth would thus be about 280 K.  This is much too cold to sustain abundant life, and is less than the average at the worst of the ice ages.

Radiation distributions: receive and emittedLife is possible on Earth only because of the presence of greenhouse gases in the atmosphere.  These are quite transparent to the visible light from the Sun, where a major part of the solar energy is concentrated.  Greenhouse gases are especially effective in absorbing the outgoing infrared radiation.  At temperatures below 500 K most of the radiation emitted by the Earth is in the infrared region of the spectrum.  There is only one broad spectral "window" at wavelengths of 8 to 13 microns where the radiation can escape.  Radiation from the Earth's surface, at a temperature of 280 K or more, is concentrated near 10 microns—in the far infrared.  Since much of the outgoing radiation is blocked by the greenhouse gases, the fourth power law tells us that the average surface temperature must be greater than 280 K in order to attain a balance with incoming solar radiation.  The actual average is near 300 K = 27 C, sufficient to sustain life on the Earth's surface.  The illustration shows how the greenhouse gases cut off part of the spectrum of radiation that would otherwise escape to space.




GLOBAL WARMING:
THE EARTH'S PRESENT CLIMATE

Beginning sometime between the late 19th century and the mid 20th century the Earth has entered a period of gradual warming.  A suspected major contributor to this warming trend is the accumulation of so-called greenhouse gases in the atmosphere: primarily carbon dioxide, methane, and chloroflurocarbons (such as Freon).  These are all produced by man's activities.  There are also other greenhouse gases such as water vapor on which man has little effect, and which have not shown rapid rises in concentration.  The evidence that these gases have actually contributed to the warming trend has been controversial, but in the past several years the evidence has become incontrovertable.

A part of the warming trend may be related to the end of the Little Ice Age, which cooled the entire world until about 170 years ago.  Another possible contributor to the warming is the dearth of major volcanic eruptions in the 20th century.  The character of the present warming is, however, quite different from warming spells of the past.  Moreover the effects of the recovery from the Little Ice Age should have peaked before the mid 20th century.  The last several decades of the 20th century also witnessed a resumption of a "normal" level of volcanic activity, so that influence can be ruled out for the past several decades. 

There is also some evidence that the weather patterns are changing.  In the past, cycles of drought were generally associated with increased warmth.  In the late twentieth century that correlation of warmth and drought has been suppressed in many regions; in some places, such as the U.S. Great Plains, the warming has been accompanied by an increasingly moist climate.  This should serve as a warning that large scale atmospheric circulation may be changing, and that the results of warming may not be simple.

The future is uncertain only in the amount of warming to be expected.  There is no disagreement among scientists that the warming will continue, and that the greenhouse gases will play a larger and larger role.  By the end of the twenty-first century, mid latitudes are expected to warm by 2 to 6 C, or possibly even more according to the most pessimistic predictions.  This may not seem like much when averaged over a year, but such temperature differences have accounted for major differences in the distributions of vegetation and life on the Earth in the distat past.




CAUSES OF GLOBAL WARMING

The present warming trend began about the year 1840, with the end of the Little Ice Age.  The cause of the Little Ice Age is not understood, but it may related to fluctuations in the output of the sun.  The warming trend was rather weak until the mid 20th century.  The general trend was difficult to discern because the total change in average temperature was far less than the daily and annual variations; and several times the trend was briefly reversed by natural year-to-year variations.  There were some cold years in the 1950's and 1960's when it seemed that the Earth was in for a new round of cooling.  Occasionally warnings were uttered that the Earth might soon be subject to another Ice Age.  Then, in the late 1960's the warming trend resumed.  That trend accelerated at the end of the century.

The primary concern of scientists is the accumulation of so-called "greenhouse gases." These include many familiar substances, both natural and man-made.  Actually greenhouse gases such as oxygen and carbon dioxide make life possible on Earth.  If there were no atmosphere, the Earth would attain an equilibrium average temperature too low to sustain life: a temperature much lower than experienced at the worst of the ice ages.  The greenhouse gases raise the temperature at the surface by preventing the escape of a portion of the infrared radiation that the Earth radiates back into space.  The Global Warming problem arises because the greenhouse gases over the past several thousand years have achieved a relatively stable natural balance, which has dictated the ways and places that man lives.  Upsetting that balance, leading to a warming rate too fast for nature and man's activities to compensate, could cause immense social and economic difficulties.

Warming by itself might be endurable; and man and nature might cope by migrating to other places; though that might require extreme poltical adjustments.  But a true catastrophe is in store if the Greenland Ice Cap and substantial portions of the Antarctic Ice Cap were to melt.  The release of such huge amounts of fresh water into the oceans could upset the oceanic circulation, and would surely flood many of the world's large cities and coastal areas.  Even a melting of part of those ice caps could raise the sea level by many meters.

There are several principal greenhouse gases whose concentrations in the atmosphere are increasing rapidly.  The greatest total increases have been observed in carbon dioxide.  Carbon dioxide is a natural product of combustion of carbon-rich fuels such as coal and wood.  The burning of petroleum products produces less carbon dioxide per energy unit, but the huge total amounts of petroleum products burnt offsets that advantage.  The next most important greenhouse gas for considerations of Global Warming is methane.  Methane is a more efficient absorber of infrared radiation, and is much more important per ton than carbon dioxide.  Methane is produced by many natural processes.  Cattle are among the most prolific producers of methane; their rich diet generates large amounts of methane.  Another class of greenhouse gases that have raised great concern are the chloro-fluorocarbons, including freon.  Chloro-fluorocarbons are especially undesirable because they also cause depletion of the stratospheric ozone layer.  These are even more effective greenhouse gases than methane.  Fortunately the release of Chloro-fluorocarbons into the atmosphere can be controlled fairly easily, and international agreements are now in place to limit their production.




THE FUTURE

If current trends continue, and if scientists are right in their predictions about the effects of accumulating greenhouse gases, future climates will be even more complex and more variable than present climates.  The temperature increases that have been reported for mid and high latitudes have generally pointed to warmer winters and relatively unchanged summers.  While trees and many other plants are extremely sensitive to the climatic conditions, the distribution of heat and moisture over the year is more important than averages.  As yet we have no simple way of predicting how plants will be affected by a temperature increase as great as several degrees.

Though significant warming has been observed in the past 50 years, the rate of warming has not yet been too great for plants to make appropriate compensations.  That situation may not hold in the future if the warming rate increases.  Another compensating factor is that the twentieth century has seen increased rainfall and moisture in those places where large amounts of the world's food is grown.  The warming over much of North America, especially on the Plains, has been accompanied by increased moisture—contrary to what might have been deduced from the association of previous warming events and droughts.

While single species may adapt to Global Warming, the response of symbiotic species and entire ecosystems may not keep up with the changes.  The problem is complicated by the fact that many species have adapted to the timing of another species; and those interrelated species may fall out of syncronism.  What happens, for instance, if a bird has to time the laying and hatching of eggs to take advantage of the flowering of a particular plant or the emergence of particular insects?  Evidence has been accumulating in recent years that such asyncronizations are indeed occuring—though no species have yet been shown to be in immediate danger.

There is no doubt that Global Warming will cause changes in the oceanic and atmospheric circulation.  As a consequence, it has been suggested that the 21st century will see more storms and violent weather.  The effects of circulation changes will especially affect the mountain regions of western North America, where there are great geographical variations in rainfall.  The northern Great Plains could also be strongly affected, since the weather there depends so critically on how the atmospheric currents make it over (or around) one of the longest north-south oriented mountain chain in the world.  The North American Cordillera has a tremendous influence on the global climate, since they are largely responsible for turning the winds and establishing the high and low pressure systems that dominate northern hemisphere weather.

In North America the effects of Global Warming will vary considerably by region.  The desert Southwest may see warmer, drier summers and winters.  The Southern Plains may experience elevated temperatures, though no one can predict with confidence how the rainfall will be affected.  In regions that already have warm climates a relatively large increase in moisture may be needed to compensate for hotter summers.  The cooler Northern Plains may actually become more favorable for agriculture.  A longer growing season could be beneficial there, if it is accompanied by increased moisture.  Since the warming there may most noticeable in the winter, more of the winter precipitation may be absorbed by the soil, which could lead to increased moisture available to growing crops.

One of the most important concerns which has arisen in recent years is the possibility that much of the Greenland and Antarctic Ice Caps could melt, causing a rise in the sea level.  The rate of melting in Greenland has increased alarmingly in recent years, but it is not yet possible to assess the likely severity.  The total rise in sea level since 1900 is still measured in millimeters; if that should become meters the results would be devastating.  It does seem likely that there will be a noticeable rise in the sea level long before the end of the twenty-first century, leading to the need for large projects to protect coastal cities.  A sea level rise of several meters or more would flood many huge coastal cities, whose total population exceeds 100 million.  The problem would only be exacerbated by the expected increase in the frequency of large cyclonic storms.  The expense of protecting cities like London or New York from such a sea level rise is unimaginable.

The north polar sea ice has also been melting much faster than expected.  This poses some serious ecological challenges, such as the survival of polar bears.  It could also lead to increased use of the Arctic Ocean by ships.  Drilling for oil in the Arctic seabed has also been suggested.  It would be a great irony if one of the principal effects of Global Warming were to be the increased production of petroleum




MITIGATION OF GLOBAL WARMING

The lack of progress in achieving world-wide reductions in the production of greenhouse gases has led some scientists and engineers to begin thinking about whether there are ways to remove the greenhouse gases from the atmosphere.  There are many ways that this might be achieved, though none of them are yet practical on a large scale.

The most obvious way to eliminate greenhouse gases would be to scrub them from the emissions at the source.  Scrubbing the gases seems relatively easy; the big problem is what to do with the waste carbon dioxide.  Carbon dioxide could be converted to relatively inert limestone and buried; the logistics of this kind of operation are quite staggering to contemplate.  Or, the carbon dioxide might be injected deep underground. 

Some favor replacing coal and petroleum with renewable combustion energy sources.  The objective would be to grow plants which absorb carbon dioxide from the air.  Then, when the plant material is burned, the net contribution to atmospheric carbon dioxide is negligible.  The idea is sound, but logistically and economically impractical at the present.

One of the more audacious schemes would to remove the carbon dioxide from the atmosphere by constructing huge scrubbers that would intercept the wind.  It is rather difficult to imagine how this could be achieved without using a significant portion of the world's energy to run the scrubbers.  Wallace Broecker, one of the leaders in Global Warming research, makes the point that such a system would be very expensive, but not more expensive than the billions of dollars of infrastructure that are already in use to process garbage and other such wastes.  Such a scheme would probably be much cheaper than the cost of moving the cities of New York, London, Hong Kong, and almost the entire nation of Bangladesh.




DEPLETION OF THE OZONE LAYER


Another major deterioration of the global environment is the depletion of the stratospheric ozone layers.  The stratospheric ozone provides a beneficial shield against solar ultraviolet radiation.  Ultraviolet radiation causes sunburn and skin damage to humans; it can also have detrimental effects on vegetation and the food crops on which we all depend.  There are, however, no significant direct effects on the climate from depletion of stratospheric ozone.

Unfortunately the stratospheric ozone layer is easily destroyed by reactions with certain compounds containing chlorine and fluorine, such as freon.  The reactions destroy ozone without affecting the amounts of the destructive agents.  Each molecule of the destructive agent can catalytically destroy hundreds of ozone molecules.  Because of their great efficiency, relatively small amounts of freon and related compounds have caused a nearly total depletion of the ozone layer at the south pole, and a considerable depletion of the ozone layer around the north pole.  The effect extends to relatively low latitudes, so Canada and northern Europe are especially susceptible to excessive ultraviolet exposure.

The problem was recognized several decades ago, and international agreements now limit the production and release of freon and similar compounds.  It will take many years before the destructive agents are fully removed from the atmosphere by natural processes, so the depletion of stratospheric ozone will be a serious concern for many decades.  In the meantime Canada and several European countries were the leaders in establishing ultraviolet exposure standards, and setting up networks of ultraviolet monitors.  Such monitors are in place in the United States, and ultraviolet exposure indices are routinely issued along with weather summaries.

There has been much controversy over the stratospheric ozone; some scientists suspect that other phenomena, such as volcanic eruptions, can also release ozone destroying gases.  Up to now, however the principal culprit appears to be chlorofluorocarbons.

The effect of ultraviolet exposures on organisms are not well understood because of strong latitude and seasonal effects.  While the dangers cannot be dismissed, it should also be kept in mind that the increases in ultraviolet exposure due to ozone depletion at mid latitudes are equivalent to the increases that would result from moving several hundred miles closer to the equator.


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